To do it, you need to use through an authenticated external SMTP service, and so you need to use a specific library as, i.e., PHPMailer.
Various code examples to use PHPMailer: http://phpmailer.worxware.com/index.php?pg=examples
Basic example use:
require_once('../class.phpmailer.php');
$mail = new PHPMailer(); // defaults to using php "mail()"
$body = file_get_contents('contents.html');
$body = eregi_replace("[\]",'',$body);
$mail->AddReplyTo("name@mydomain.com","First Last");
$mail->SetFrom('name@mydomain.com', 'First Last');
$mail->AddReplyTo("name@mydomain.com","First Last");
$address = "someone@yourdomain.com";
$mail->AddAddress($address, "John Smith");
$mail->Subject = "PHPMailer Test Subject via mail(), basic";
$mail->AltBody = "To view the message, please use an HTML compatible email viewer!"; // optional, comment out and test
$mail->MsgHTML($body);
$mail->AddAttachment("images/phpmailer.gif"); // attachment
$mail->AddAttachment("images/phpmailer_mini.gif"); // attachment
if(!$mail->Send()) {
echo "Mailer Error: " . $mail->ErrorInfo;
} else {
echo "Message sent!";
}